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Fluoroglycofen Ethyl Weed Control Herbicides 95% TC CCC

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Fluoroglycofen Ethyl Weed Control Herbicides 95% TC CCC

Fluoroglycofen Ethyl Weed Control Herbicides 95% TC CCC
Fluoroglycofen Ethyl Weed Control Herbicides 95% TC CCC

Large Image :  Fluoroglycofen Ethyl Weed Control Herbicides 95% TC CCC

Product Details:
Place of Origin: China
Brand Name: EE
Certification: CCC
Model Number: 0697
Payment & Shipping Terms:
Minimum Order Quantity: 1KL/1ton
Price: USD1-2/KG
Packaging Details: 100g/bag,200g/bag, 500g/bag, 1kg/bag, 25kg/bag
Delivery Time: 25-35day
Payment Terms: L/C, T/T, Western Union, MoneyGram
Supply Ability: 4ton/ Day
Detailed Product Description
CAS No.: 77501-60-1 MF: C18H13ClF3NO7
Other Names: Benzoic Acid State: Liquid
Purity: 95% TC Shelf Life: 2 Years, 2~3 Years
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Fluoroglycofen Ethyl Weed Control Herbicides


Weed Control Herbicides 95% TC


CCC Fluoroglycofen Ethyl Herbicides



Chemical Abstracts name ethyl (R)-2-[4-[(6-chloro-2-benzoxazolyl)oxy]phenoxy]propanoate CAS RN [71283–80–2] Development codes Hoe 046360 (Hoechst); AE F046360 (AgrEvo) Smiles code CCOC(=O)[C@@H](C)Oc1ccc(Oc2nc3ccc(Cl)cc3o2)cc1;without stereochemistry:CCOC(=O)C(C)Oc1ccc(Oc2nc3ccc(Cl)cc3o2)cc1
Common name fenoxaprop-P (BSI, E-ISO); fénoxaprop-P ((m) F-ISO)
IUPAC name (R)-2-[4-(6-chloro-1,3-benzoxazol-2-yloxy)phenoxy]propionic acid; (R)-2-[4-(6-chlorobenzoxazol-2-yloxy)phenoxy]propionic acid
Chemical Abstracts name (R)-2-[4-[(6-chloro-2-benzoxazolyl)oxy]phenoxy]propanoic acid CAS RN [113158–40–0] Development codes Hoe 088406 (Hoechst); AE F088406 (AgrEvo)
Mol. wt. 361.8 M.f. C18H16ClNO5 Form White, odourless solid. M.p. 89–91 °C V.p. 5.3 × 10 mPa (20 °C) Kow logP = 4.58 Henry 2.74 × 10 Pa m mol (calc.) S.g./density 1.3 (20 °C) Solubility In water 0.7 mg/l (pH 5.8, 20 °C). In acetone, toluene and ethyl acetate >200, methanol 43 (all in g/l, 20 °C). Stability Fenoxaprop-P-ethyl is stable for 90 d at 50 °C. Not sensitive to light. Hydrolysis DT50 2.8 d (pH 4), 19.2 d (pH 5), 23.2 d (pH 7), 0.6 d (pH 9) (25 °C) (EFSA Sci. Rep. (2007) 121, 1–76).
Mol. wt. 333.7 M.f. C16H12ClNO5 Form Light beige, weakly pungent, fine powder. M.p. 155–161 °C V.p. 3.5 × 10 mPa Kow logP = 1.83–0.24 (pH 5–9) Henry 1.91 × 10 Pa m mol(pH 7.0, calc.) S.g./density c. 1.5 (20 °C) Solubility In water 0.27 (pH 5.1), 61 (pH 7.0) (both in g/l, 20 °C). In acetone 80, toluene 0.5, ethyl acetate 36, methanol 34 (all in g/l, 20 °C).
History The herbicidal enantiomer of fenoxaprop was reported by H. P. Huff et al. (Proc. Br. Crop Prot. Conf. - Weeds, 1989, 2, 717). Introduced by Hoechst AG (now Bayer AG) in 1988.
Manufacturers Bayer CropScience; Anhui Huaxing; Cheminova; Fengle; JIE; Jingma; Kajo; Sharda; Sundat; Tide; Zhejiang Hisun
Biochemistry Fatty acid synthesis inhibition in grasses, by inhibition of acetyl CoA carboxylase (ACCase). Rapidly hydrolysed in plants to the acid, which is still herbicidally active. Mode of action Fenoxaprop-P-ethyl is a selective herbicide with contact and systemic action, absorbed principally by the leaves, with translocation both acropetally and basipetally to the roots or rhizomes.
Uses Post-emergence control of annual and perennial grass weeds in potatoes, beans, soya beans, beets, vegetables, peanuts, flax, oilseed rape and cotton; and (when applied with the herbicide safener mefenpyr-diethyl) annual and perennial grass weeds and wild oats in wheat, rye, triticale and, depending on ratio, in some varieties of barley. Applied at 40–90 g/ha in cereals (max. 83 g/ha in EU) and at 30–140 g/ha in broad-leaved crops. Phytotoxicity Non-phytotoxic to broad-leaved crops.
Formulation types EC; EW; SE.
Selected products 'Furore Super' (Bayer CropScience); 'Foxtrot' (Cheminova); 'Masaldo' (Crop Health); 'Sunfenoxa-P-Ethyl' (Sundat); mixtures 'Hussar' (+ iodosulfuron-methyl-sodium + mefenpyr-diethyl) (Bayer CropScience); 'Puma' (+ mefenpyr-diethyl) (Bayer CropScience); 'Puma Super' (+ mefenpyr-diethyl) (Bayer CropScience). Other products 'Acclaim Super' (Bayer CropScience); 'Bugle' (Bayer CropScience); 'Depon Super' (Bayer CropScience); 'Option II' (Bayer CropScience); 'Rumpas' (Bayer CropScience); 'Silverado' (Bayer CropScience); 'Starice' (Bayer CropScience); 'Triumph' (Bayer CropScience); 'Whip 360' (Bayer CropScience); 'Whip Super' (Bayer CropScience); 'Felmon' (Efthymiadis); 'Jupiter' (P I Industries); 'Orion' (Biostadt); 'Ralon' (Nufarm Deutschland); mixtures 'Baghera' (+ diclofop-methyl + mefenpyr-diethyl) (Bayer CropScience); 'Cheetah Super' (+ mefenpyr-diethyl) (Bayer CropScience); 'Cheyenne' (+ MCPA-2-ethylhexyl) (Bayer CropScience); 'Corniche' (+ diclofop-methyl + mefenpyr-diethyl) (Bayer CropScience); 'Dakota' (+ MCPA-2-ethylhexyl) (Bayer CropScience); 'Djinn' (+ isoproturon + mefenpyr-diethyl) (Bayer CropScience); 'Dopler' (+ diclofop-methyl + mefenpyr-diethyl) (Bayer CropScience); 'Horizon 2000' (+ fluazifop-P-butyl) (Bayer CropScience); 'Hussar OF' (+ iodosulfuron-methyl-sodium + mefenpyr-diethyl) (Bayer CropScience); 'Podium S' (+ clethodim) (Bayer CropScience); 'Preclaim' (+ pendimethalin) (Bayer CropScience); 'Proper energy' (+ mefenpyr-diethyl) (Bayer CropScience); 'Puma Extra' (+ isoproturon) (Bayer CropScience); 'Puma Power' (+ mefenpyr-diethyl) (Bayer CropScience); 'Puma S' (+ mefenpyr-diethyl) (Bayer CropScience); 'Puma X' (+ isoproturon) (Bayer CropScience); 'Ricestar' (+ isoxadifen-ethyl) (Bayer CropScience); 'Ricestar xtra' (+ ethoxysulfuron) (Bayer CropScience); 'Tigress Ultra' (+ diclofop-methyl) (Bayer CropScience); 'Tiller' (+ 2,4-D-2-ethylhexyl + MCPA-2-ethylhexyl) (Bayer CropScience); 'Tiller Gold' (+ ethoxysulfuron) (Bayer CropScience); 'Turbo' (+ ethoxysulfuron + isoxadifen-ethyl) (Bayer CropScience); 'Wildcat' (+ mefenpyr-diethyl) (Bayer CropScience); 'Zeus' (+ diclofop-methyl + mefenpyr-diethyl) (Bayer CropScience); 'Bledor' (+ diclofop-methyl + mefenpyr-diethyl) (Siapa); 'Fenuron Super-Set' (+ chlorotoluron) (Nufarm Deutschland); 'Fusion' (+ fluazifop-P-butyl) (Bayer CropScience, Syngenta); 'Ralon Super' (+ mefenpyr-diethyl) (Nufarm Deutschland). Discontinued products 'Silban' * (IPESA); mixtures 'Tigress' * (+ diclofop-methyl) (AgrEvo); 'Tiller' * (+ 2,4-D-isoctyl + MCPA-2-ethylhexyl) (AgrEvo); 'Twister' * (+ fluazifop-P-butyl + fomesafen-sodium) (Syngenta).
Product analysis by hplc with uv detection; enantiomeric purity by chiral phase separation, followed by uv detection (CIPAC Handbook, 2000, J, 51). Details are also available from Bayer CropScience.
EFSA Sci. Rep. (2007) 121, 1–76. 91/414/EC Annex I status Included, 2008/66/EC.
Oral Acute oral LD50 for rats 3150–4000, mice >5000 mg/kg. Skin and eye Acute percutaneous LD50 for rats >2000 mg/kg. Inhalation LC50 (4 h) for rats >1.224 mg/l air. NOEL (90 d) for rats 0.75 mg/kg b.w. daily (10 ppm), for mice 1.4 mg/kg b.w. daily (10 ppm), for dogs 15.9 mg/kg b.w. daily (400 ppm). ADI/RfD (EC) 0.01 mg/kg b.w. [2008].
Birds Acute oral LD50 for bobwhite quail >2000 mg/kg. Fish LC50 (96 h) for bluegill sunfish 0.58, rainbow trout 0.46 mg/l. Daphnia LC50 (48 h) 0.56 (pH 8.0–8.4), 2.7 (pH 7.7–7.8) mg/l. Algae LC50 (72 h) for Scenedesmus subspicatus 0.51 mg/l. Bees LC50 (oral) >199 μg/bee; (contact) >200 μg/bee (EFSA Sci. Rep.). Worms LC50 (14 d) for Eisenia foetida >1000 mg/kg soil.
Plants In plants, fenoxaprop-P-ethyl is metabolised via fenoxaprop-P to 6-chloro-2,3-dihydrobenzoxazol-2-one. Soil/Environment In soil, fenoxaprop-P-ethyl is rapidly hydrolysed to fenoxaprop-P (A. E. Smith, J. Agric. Food Chem., 1985, 33, 483); DT50 1–10 d.
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